Nuclear fission Totally Explained

Everything about Nuclear Fission totally explained

Nuclear fission is the splitting of the nucleus of an atom into parts (lighter nuclei) often producing free neutrons and other smaller nuclei, which may eventually produce photons (in the form of gamma rays). Fission of heavy elements is an exothermic reaction which can release large amounts of energy both as electromagnetic radiation and as kinetic energy of the fragments (heating the bulk material where fission takes place). Fission is a form of elemental transmutation because the resulting fragments are not the same element as the original atom.
Nuclear fission produces energy for nuclear power and to drive the explosion of nuclear weapons. Both uses are made possible because certain substances called nuclear fuels undergo fission when struck by free neutrons and in turn generate neutrons when they break apart. This makes possible a self-sustaining chain reaction that releases energy at a controlled rate in a nuclear reactor or at a very rapid uncontrolled rate in a nuclear weapon.
The amount of free energy contained in nuclear fuel is millions of times the amount of free energy contained in a similar mass of chemical fuel such as gasoline, making nuclear fission a very tempting source of energy; however, the products of nuclear fission are radioactive and remain so for significant amounts of time, giving rise to a nuclear waste problem. Concerns over nuclear waste accumulation and over the destructive potential of nuclear weapons may counterbalance the desirable qualities of fission as an energy source, and give rise to ongoing political debate over nuclear power.

Physical overview

Nuclear fission differs from other forms of radioactive decay in that it can be harnessed and controlled via a chain reaction: free neutrons released by each fission event can trigger yet more events, which in turn release more neutrons and cause more fissions. Chemical isotopes that can sustain a fission chain reaction are called nuclear fuels, and are said to be fissile. The most common nuclear fuels are ²³⁵U (the isotope of uranium with an atomic mass of 235 and of use in nuclear reactors) and ²³⁹Pu (the isotope of plutonium with an atomic mass of 239). These fuels break apart into a bimodal range of chemical elements with atomic masses centering near 95 and 135 u (fission products). Most nuclear fuels undergo spontaneous fission only very slowly, decaying mainly via an alpha/beta decay chain over periods of millennia to eons. In a nuclear reactor or nuclear weapon, most fission events are induced by bombardment with another particle such as a neutron.
   Typical fission events release about two hundred million eV of energy for each fission event. By contrast, most chemical oxidation reactions (such as burning coal or TNT) release at most a few eV per event, so nuclear fuel contains at least ten million times more usable energy than does chemical fuel. The energy of nuclear fission is released as kinetic energy of the fission products and fragments, and as electromagnetic radiation in the form of gamma rays; in a nuclear reactor, the energy is converted to heat as the particles and gamma rays collide with the atoms that make up the reactor and its working fluid, usually water or occasionally heavy water. Nuclear fission of heavy elements produces energy because the specific binding energy (binding energy per mass) of intermediate-mass nuclei with atomic numbers and atomic masses close to ⁶¹Ni and ⁵⁶Fe is greater than the specific binding energy of very heavy nuclei, so that energy is released when heavy nuclei are broken apart.
   The total rest masses of the fission products (Mp) from a single reaction is less than the mass of the original fuel nucleus (M). The excess mass Δm = M - Mp is the invariant mass of the energy that's released as photons (gamma rays) and kinetic energy of the fission fragments, according to the mass-energy equivalence formula E = mc².
   In nuclear fission events the nuclei may break into any combination of lighter nuclei, but the most common event isn't fission to equal mass nuclei of about mass 120; the most common event (depending on isotope and process) is a slightly unequal fission in which one daughter nucleus has a mass of about 90 to 100 u and the other the remaining 130 to 140 u (External Link

). Unequal fissions are energetically more favorable because this allows one product to be closer to the energetic minimum near mass 60 u (only a quarter of the average fissionable mass), while the other nucleus with mass 135 u is still not far out of the range of the most tightly bound nuclei (another statement of this, is that the atomic binding energy curve is slightly steeper to the left of mass 120 u than to the right of it).
The variation in specific binding energy with atomic number is due to the interplay of the two fundamental forces acting on the component nucleons (protons and neutrons) that make up the nucleus. Nuclei are bound by an attractive strong nuclear force between nucleons, which overcomes the electrostatic repulsion between protons. However, the strong nuclear force acts only over extremely short ranges, since it follows a Yukawa potential. For this reason large nuclei are less tightly bound per unit mass than small nuclei, and breaking a very large nucleus into two or more intermediate-sized nuclei releases energy.
Because of the short range of the strong binding force, large nuclei must contain proportionally more neutrons than do light elements, which are most stable with a 1-1 ratio of protons and neutrons. Extra neutrons stabilize heavy elements because they add to strong-force binding without adding to proton-proton repulsion. Fission products have, on average, about the same ratio of neutrons and protons as their parent nucleus, and are therefore usually unstable because they've proportionally too many neutrons compared to stable isotopes of similar mass. This is the fundamental cause of the problem of radioactive high level waste from nuclear reactors. Fission products tend to be beta emitters, emitting fast-moving electrons to conserve electric charge as excess neutrons convert to protons inside the nucleus of the fission product atoms. The most common nuclear fuels, ²³⁵U and ²³⁹Pu, are not major radiologic hazards by themselves: ²³⁵U has a half-life of approximately 700 million years, and although ²³⁹Pu has a half-life of only about 24,000 years, it's a pure alpha particle emitter and hence not particularly dangerous unless ingested. Once a fuel element has been used, the remaining fuel material is intimately mixed with highly radioactive fission products that emit energetic beta particles and gamma rays. Some fission products have half-lives as short as seconds; others have half-lives of tens of thousands of years, requiring long-term storage in facilities such as Yucca Mountain until the fission products decay into non-radioactive stable isotopes.

Chain reactions

Many heavy elements, such as uranium, thorium, and plutonium, undergo both spontaneous fission, a form of radioactive decay and induced fission, a form of nuclear reaction. Elemental isotopes that undergo induced fission when struck by a free neutron are called fissionable; isotopes that undergo fission when struck by a thermal, slow moving neutron are also called fissile. A few particularly fissile and readily obtainable isotopes (notably ²³⁵U and ²³⁹Pu) are called nuclear fuels because they can sustain a chain reaction and can be obtained in large enough quantities to be useful.
All fissionable and fissile isotopes undergo a small amount of spontaneous fission which releases a few free neutrons into any sample of nuclear fuel. Such neutrons would escape rapidly from the fuel and become a free neutron, with a half-life of about 15 minutes before they decayed to protons and beta particles. However, neutrons almost invariably impact and are absorbed by other nuclei in the vicinity long before this happens (newly-created fission neutrons are moving at about 7% of the speed of light, and even moderated neutrons are moving at about 8 times the speed of sound). Some neutrons will impact fuel nuclei and induce further fissions, releasing yet more neutrons. If enough nuclear fuel is assembled into one place, or if the escaping neutrons are sufficiently contained, then these freshly generated neutrons outnumber the neutrons that escape from the assembly, and a sustained nuclear chain reaction will take place.
An assembly that supports a sustained nuclear chain reaction is called a critical assembly or, if the assembly is almost entirely made of a nuclear fuel, a critical mass. The word "critical" refers to a cusp in the behavior of the differential equation that governs the number of free neutrons present in the fuel: if less than a critical mass is present, then the amount of neutrons is determined by radioactive decay, but if a critical mass or more is present, then the amount of neutrons is controlled instead by the physics of the chain reaction. The actual mass of a critical mass of nuclear fuel depends strongly on the geometry and surrounding materials. Not all fissionable isotopes can sustain a chain reaction. For example, ²³⁸U, the most abundant form of uranium, is fissionable but not fissile: it undergoes induced fission when impacted by an energetic neutron with over 1 MeV of kinetic energy. But too few of the neutrons produced by ²³⁸U fission are energetic enough to induce further fissions in ²³⁸U, so no chain reaction is possible with this isotope. Instead, bombarding ²³⁸U with slow neutrons causes it to absorb them (becoming ²³⁹U) and decay by beta emission to ²³⁹Np which then decays again by the same process to ²³⁹Pu; that process is used to manufacture ²³⁹Pu in breeder reactors, but doesn't contribute to a neutron chain reaction. Fissionable, non-fissile isotopes can be used as fission energy source even without a chain reaction. Bombarding ²³⁸U with fast neutrons induces fissions, releasing energy as long as the external neutron source is present. That effect is used to augment the energy released by modern thermonuclear weapons, by jacketing the weapon with ²³⁸U to react with neutrons released by nuclear fusion at the center of the device.

Fission reactors

Critical fission reactors are the most common type of nuclear reactor. In a critical fission reactor, neutrons produced by fission of fuel atoms are used to induce yet more fissions, to sustain a controllable amount of energy release. Devices that produce engineered but non-self-sustaining fission reactions are subcritical fission reactors. Such devices use radioactive decay or particle accelerators to trigger fissions. Critical fission reactors are built for three primary purposes, which typically involve different engineering trade-offs to take advantage of either the heat or the neutrons produced by the fission chain reaction:

power reactors are intended to produce heat for nuclear power, either as part of a generating station or a local power system such as a nuclear submarine.
research reactors are intended to produce neutrons and/or activate radioactive sources for scientific, medical, engineering, or other research purposes.
breeder reactors are intended to produce nuclear fuels in bulk from more abundant isotopes. The better known fast breeder reactor makes ²³⁹Pu (a nuclear fuel) from the naturally very abundant ²³⁸U (not a nuclear fuel). Thermal breeder reactors previously tested using ²³²Th continue to be studied and developed. While, in principle, all fission reactors can act in all three capacities, in practice the tasks lead to conflicting engineering goals and most reactors have been built with only one of the above tasks in mind. (There are several early counter-examples, such as the Hanford N reactor, now decommissioned). Power reactors generally convert the kinetic energy of fission products into heat, which is used to heat a working fluid and drive a heat engine that generates mechanical or electrical power. The working fluid is usually water with a steam turbine, but some designs use other materials such as gaseous helium. Research reactors produce neutrons that are used in various ways, with the heat of fission being treated as an unavoidable waste product. Breeder reactors are a specialized form of research reactor, with the caveat that the sample being irradiated is usually the fuel itself, a mixture of ²³⁸U and ²³⁵U.
For a more detailed description of the physics and operating principles of critical fission reactors, see nuclear reactor physics. For a description of their social, political, and environmental aspects, see nuclear reactor.

Fission bombs

One class of nuclear weapon, a fission bomb (not to be confused with the fusion bomb), otherwise known as an atomic bomb or atom bomb, is a fission reactor designed to liberate as much energy as possible as rapidly as possible, before the released energy causes the reactor to explode (and the chain reaction to stop). Development of nuclear weapons was the motivation behind early research into nuclear fission: the Manhattan Project of the U.S. military during World War II carried out most of the early scientific work on fission chain reactions, culminating in the Little Boy and Fat Man and Trinity bombs that were exploded over test sites, the cities Hiroshima, and Nagasaki, Japan in August of 1945.
Even the first fission bombs were thousands of times more explosive than a comparable mass of chemical explosive. For example, Little Boy weighed a total of about four tons (of which 60 kg was nuclear fuel) and was long; it also yielded an explosion equivalent to about 15 kilotons of TNT, destroying a large part of the city of Hiroshima. Modern nuclear weapons (which include a thermonuclear fusion as well as one or more fission stages) are literally hundreds of times more energetic for their weight than the first pure fission atomic bombs, so that a modern single missile warhead bomb weighing less than 1/8th as much as Little Boy (see for example W88) has a yield of 475,000 tons of TNT, and could bring destruction to 10 times the city area. While the fundamental physics of the fission chain reaction in a nuclear weapon is similar to the physics of a controlled nuclear reactor, the two types of device must be engineered quite differently (see nuclear reactor physics). It is impossible to convert a nuclear reactor to cause a true nuclear explosion, or for a nuclear reactor to explode the way a nuclear explosive does, (though partial fuel meltdowns and steam explosions have occurred), and similarly difficult to extract useful power from a nuclear explosive (though at least one rocket propulsion system, Project Orion, was intended to work by exploding fission bombs behind a massively padded vehicle!).
The strategic importance of nuclear weapons is a major reason why the technology of nuclear fission is politically sensitive. Viable fission bomb designs are, arguably, within the capabilities of bright undergraduates (see John Aristotle Phillips) being incredibly simple, but nuclear fuel to realize the designs is thought to be difficult to obtain being rare (see uranium enrichment and nuclear fuel cycle).

History

Unlike nuclear fusion which occurs in stars, natural nuclear fission is less common. At three ore deposits at Oklo in Gabon, sixteen sites have been discovered at which self-sustaining nuclear fission took place approximately 1.5 billion years ago.
   While many believe that Ernest Rutherford became the first person to deliberately split the atom by bombarding nitrogen with naturally occurring alpha particles from radioactive material and observing a proton emitted with energy higher than the alpha particle, this is incorrect. Rutherford forced protons out of the nucleus but didn't split the nucleus, as a fission reaction requires. In 1932 his students John Cockcroft and Ernest Walton, working under Rutherford's direction, attempted to split the nucleus by entirely artificial means, using a particle accelerator to bombard lithium with protons thereby producing two alpha particles. This did split the nucleus, but nevertheless wasn't quite the classical nuclear fission which is induced in heavy nuclei, because the daughter fragments are alpha particles-- already well-known fragments of excited nuclei, and not considered to be a truly new phenomenon, even if two of them had been produced, and nothing else.
   The first clear induced (manmade) nuclear fission as we know it occurred in results of the bombardment of uranium by neutrons, which proved interesting and puzzling. First studied by Enrico Fermi and his colleagues in 1934, these results were not properly interpreted and understood until several years later.
   After the Fermi publication, Lise Meitner, Otto Hahn and Fritz Strassmann began performing similar experiments in Germany. Meitner, an Austrian Jew, lost her citizenship with the Anschluss in 1938. She fled and wound up in Sweden, but continued to collaborate by mail and through meetings with Hahn in Sweden. By coincidence her nephew Otto Robert Frisch, also a refugee, was also in Sweden when Meitner received a letter from Hahn describing his chemical proof that some of the product of the bombardment of uranium with neutrons, was barium and not barium's much heavier chemical sister element radium (barium's atomic weight is half that of uranium). Frisch was skeptical, but Meitner believed Hahn was too good a chemist to have made a mistake. Marie Curie had been separating barium from radium for many years, and the techniques were well-known. According to Frisch:

Was it a mistake? No, said Lise Meitner; Hahn was too good a chemist for that. But how could barium be formed from uranium? No larger fragments than protons or helium nuclei (alpha particles) had ever been chipped away from nuclei, and to chip off a large number not nearly enough energy was available. Nor was it possible that the uranium nucleus could have been cleaved right across. A nucleus wasn't like a brittle solid that can be cleaved or broken; George Gamow had suggested early on, and Bohr had given good arguments that a nucleus was much more like a liquid drop. Perhaps a drop could divide itself into two smaller drops in a more gradual manner, by first becoming elongated, then constricted, and finally being torn rather than broken in two? We knew that there were strong forces that would resist such a process, just as the surface tension of an ordinary liquid drop tends to resist its division into two smaller ones. But nuclei differed from ordinary drops in one important way: they were electrically charged, and that was known to counteract the surface tension.

The charge of a uranium nucleus, we found, was indeed large enough to overcome the effect of the surface tension almost completely; so the uranium nucleus might indeed resemble a very wobble unstable drop, ready to divide itself at the slightest provocation, such as the impact of a single neutron. But there was another problem. After separation, the two drops would be driven apart by their mutual electric repulsion and would acquire high speed and hence a very large energy, about 200 MeV in all; where could that energy come from? ...Lise Meitner... worked out that the two nuclei formed by the division of a uranium nucleus together would be lighter than the original uranium nucleus by about one-fifth the mass of a proton. Now whenever mass disappears energy is created, according to Einstein's formula E=mc2, and one-fifth of a proton mass was just equivalent to 200MeV. So here was the source for that energy; it all fitted!

In December 1938, the German chemists Otto Hahn and Fritz Strassmann sent a manuscript to Naturwissenschaften reporting they'd detected the element barium after bombarding uranium with neutrons; simultaneously, they communicated these results to Lise Meitner. Meitner, and her nephew Otto Robert Frisch, correctly interpreted these results as being nuclear fission. Frisch confirmed this experimentally on 13 January 1939. In 1944, Hahn received the Nobel Prize for Chemistry for the discovery of nuclear fission. Some historians have documented the history of the discovery of nuclear fission and believe Meitner should have been awarded the Nobel Prize with Hahn.
   Meitner’s and Frisch’s interpretation of the work of Hahn and Strassmann crossed the Atlantic Ocean with Niels Bohr, who was to lecture at Princeton University. Isidor Isaac Rabi and Willis Lamb, two Columbia University physicists working at Princeton, heard the news and carried it back to Columbia. Rabi said he told Enrico Fermi; Fermi gave credit to Lamb. Bohr soon thereafter went from Princeton to Columbia to see Fermi. Not finding Fermi in his office, Bohr went down to the cyclotron area and found Herbert L. Anderson. Bohr grabbed him by the shoulder and said: “Young man, let me explain to you about something new and exciting in physics.” It was clear to a number of scientists at Columbia that they should try to detect the energy released in the nuclear fission of uranium from neutron bombardment. On 25 January 1939, a Columbia University team conducted the first nuclear fission experiment in the United States, which was done in the basement of Pupin Hall; the members of the team were Herbert L. Anderson, Eugene T. Booth, John R. Dunning, Enrico Fermi, G. Norris Glasoe, and Francis G. Slack. The next day, the Fifth Washington Conference on Theoretical Physics began in Washington, D.C. under the joint auspices of The George Washington University and the Carnegie Institution of Washington. There, the news on nuclear fusion was spread even further, which fostered many more experimental demonstrations. Frédéric Joliot-Curie's team in Paris discovered that secondary neutrons are released during uranium fission, thus making a nuclear chain-reaction feasible. The figure of about two neutrons being emitted with nuclear fission of uranium was verified independently by Leo Szilard and Walter Henry Zinn. The number of neutrons emitted with nuclear fission of uranium-235 was then reported at 3.5/fission, and later corrected to 2.6/fission by Frédéric Joliot-Curie, Hans von Halban and Lew Kowarski.
   "Chain reactions" at that time were a known phenomenon in chemistry, but the analogous process in nuclear physics, using neutrons, had been foreseen as early as 1933 by Leo Szilard, although Szilard at that time had no idea with what materials the process might be initiated (Szilard thought it might be done with light neutron-rich elements elements). Szilard, a Hungarian born Jew, also fled mainland Europe after Hitler's rise, eventually landing in the US.
   With the news of fission neutrons from uranium fission, Szilard immediately understood the possibility of a nuclear chain reaction using uranium. In the summer, Fermi and Szilard proposed the idea of a nuclear reactor (pile) to mediate this process. The pile would use natural uranium as fuel, and graphite as the moderator of neutron energy (it had previously been shown by Fermi that neutrons were far more effectively captured by atoms if they were moving slowly, a process called moderation when the neutrons were slowed after being released from a fission event in a nuclear reactor).
   In August Hungarian-Jewish refugees Szilard, Teller and Wigner thought that the Germans might make use of the fission chain reaction, and persuaded Austrian-Jewish refugee Einstein to warn President Roosevelt of the this possible German menace. The letter suggested the possibility of a uranium bomb deliverable by ship, which would destroy "an entire harbor and much of the surrounding countryside." The President received the letter on 1939.10.11 shortly after WWII began in Europe, but two years before U.S. entry into it.
   In England, James Chadwick proposed an atomic bomb utilizing natural uranium, based on a paper by Rudolf Peierls with the mass needed for critical state being 30-40 tons. In America, J. Robert Oppenheimer thought that a cube of uranium deuteride 10 cm on a side (about 11 kg of uranium) might "blow itself to hell." In this design it was still thought that a moderator would need to be used for nuclear bomb fission (this turned out not to be the case if the fissile isotope was separated).
   In December, Heisenberg delivered a report to the Germany Department of War on the possibility of a uranium bomb.
   In Birmingham, England Otto Robert Frisch teamed up with Rudolf Peierls who had also fled German anti-Jewish laws. They conceived the idea of utilizing a purified isotope of uranium, uranium-235, and worked out that an enriched uranium bomb could have a critical mass of only 600 grams, instead of tons, and that the resulting explosion would be tremendous. (The amount actually turned out to be 15 kg, although several times this amount was used in the actual uranium (Little Boy) bomb). In February 1940 they delivered the Frisch-Peierls memorandum. Ironically, they were still officially considered "enemy aliens" at the time. Glenn Seaborg, Joe Kennedy, Art Wahl and Italian-Jewish refugee Emilio Segrè shortly discovered plutonium-239 in the decay products of uranium-239 produced by bombarding uranium-238 with neutrons, and determined it to be fissionable like U-235. (Lawrence controversially dropped Segrè's pay by half when he learned he was trapped in the U.S. by Mussolini's race laws.)
   On June 28, 1941, the Office of Scientific Research and Development was formed in the U.S. to mobilize scientific resources and apply the results of research to national defense. In September, Fermi assembled his first nuclear "pile" or reactor, in an attempt to create a slow neutron induced chain reaction in uranium, but the experiment failed for lack of proper materials, or not enough of the materials which were available.
   Producing a fission chain reaction in natural uranium fuel was found to be far from trivial. Early nuclear reactors didn't use isotopically enriched uranium, and in consequence they were required to use large quantities of highly purified graphite as neutron moderation materials. Use of ordinary water (as opposed to heavy water) in nuclear reactors requires enriched fuel--- the partial separation and relative enrichment of the rare ²³⁵U isotope from the far more common ²³⁸U isotope. Typically, reactors also require inclusion of extremely chemically pure neutron moderator materials such as deuterium (in heavy water), helium, beryllium, or carbon, the latter usually as graphite. (The high purity for carbon is required because many chemical impurities such as the boron-10 component of natural boron, are very strong neutron absorbers and thus poison the chain reaction.)
   Production of such materials at industrial scale had to be solved for nuclear power generation and weapons production to be accomplished. Up to 1940, the total amount of uranium metal produced in the USA wasn't more than a few grams, and even this was of doubtful purity; of metallic beryllium not more than a few kilograms; concentrated deuterium oxide (heavy water) not more than a few kilograms. Finally, carbon had never been produced in quantity with anything like the purity required of a moderator.
   The problem of producing large amounts of high purity uranium was solved by Frank Spedding using the thermite process. Ames Laboratory was established in 1942 to produce the large amounts of natural (unenriched) uranium metal that would be necessary for the research to come. The success of the Chicago Pile-1 which used unenriched (natural) uranium, like all of the atomic "piles" which produced the plutonium for the atomic bomb, was also due specifically to Szilard's realization that very pure graphite could be used for the moderator of even natural uranium "piles". In wartime Germany, failure to appreciate the qualities of very pure graphite led to reactor designs dependent on heavy water, which in turn was denied the Germans by Allied attacks in Norway, where heavy water was produced. These difficulties prevented the Nazis from building a nuclear reactor capable of criticality during the war.
   Unknown until 1972 (but postulated by Paul Kuroda in 1956), when French physicist Francis Perrin discovered the Oklo Fossil Reactors, it was realized that nature had beaten humans to the punch. Large-scale natural uranium fission chain reactions, moderated by normal water, had occurred some 2,000 million years in the past. This ancient process was able to use normal water as a moderator only because 2,000 million years in the past, natural uranium was highly "enriched" with the shorter-lived fissile isotope ²³⁵U, as compared with natural uranium available today.
   For more detail on the early development of the first nuclear reactors and nuclear weapons, see Manhattan Project.

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